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Digitale Medien

Hydrogen transfer in slurries of carbon supported catalyst (HPO process) (1988)

Lindner, D. ; Werner, M. ; Schumpe, A.

Hoboken, NJ : Wiley-Blackwell

AIChE Journal 34 (1988), S. 1691-1697

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Details

ISSN: 0001-1541

Schlagwort(e): Chemistry ; Chemical Engineering

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung

Notizen: The effect of suspended activated carbon on gas/liquid mass transfer is studied for the Pd/C-catalyzed hydrogenation of nitrate to hydroxylamine (HPO process). In a bubble column and in a stirred autoclave, physical mass transfer (kLa) in the concentrated salt solution is improved by more than a factor of three by the catalyst. Chemical absorption enhancement by the zero-order catalytic reaction is insignificant at the employed catalyst diameter (40 μm), but hydroxylamine selectivity depends on the absorption regime.

Zusätzliches Material: 8 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/aic.690341013

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