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Predictive correlation for binary diffusion coefficients in dense carbon dioxide (1992)

Funazukuri, Toshitaka ; Ishiwata, Yoshihisa ; Wakao, Noriaki

Hoboken, NJ : Wiley-Blackwell

AIChE Journal 38 (1992), S. 1761-1768

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ISSN: 0001-1541

Keywords: Chemistry ; Chemical Engineering

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology

Notes: Binary diffusion coefficients of some organic compounds in carbon dioxide at 313.2 K and 16.0/25.0 MPa were measured by using the Taylor-Aris tracer response technique. We propose a new correlation of Schmidt numbers as a function of solvent molar volumes for predicting binary diffusion coefficients in dence CO2 and self-diffusion coefficients of dense CO2. The correlation was also found to be valid for predicting self-diffusion coefficients of dense CH4 at Fv/A* 〈 40 or v2/(ṽ2)0 〉 1.62.

Additional Material: 7 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/aic.690381109

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