ISSN:
0001-1541
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
Two new nanofiltration membranes, an organomineral (titania-Nafion) medium and an inorganic (γAl2O3) medium, were studied using single or mixed solutions of monovalent or divalent ions. The experimental results not only confirm previous findings concerning the treatment of electrolytic solutions using charged nanofiltration membranes, but provide additional data notably for microporous membranes. A simple model based on the Nernst-Planck equation is proposed; its simplicity is related to the nature of the two membranes tested, for which the diffusion terms may easily be disregarded. It highlights the importance of the potential difference that forms on the membrane and explains most of the observed rejection results. In addition, ionic plugging of micropores may play a part with regards to rejection and flow depending on working conditions.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aic.690420912