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Poly[d(A-T)-Cs+] conformations studied by IR spectroscopy (1987)

Adam, S. ; Bourtayre, P. ; Liquier, J. ; [et al.]

New York : Wiley-Blackwell

Biopolymers 26 (1987), S. 251-260

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ISSN: 0006-3525

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Infrared absorption and ir linear dichroism measurements have been performed on poly[d(A-T)-Cs+] films at various relative humidities. At high relative humidity, samples are in a B form; at low relative humidity, in a C form. The B → C conformational transition is shown to be a noncooperative one corresponding to a gradual evolution of the backbone geometry of the polynucleotide within the B family. the C-form-type spectrum is characteristic of an alternated phosphodiester chain with a dinucleotidic repeat unit.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/bip.360260207

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