ISSN:
0032-3888
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Recent studies of the dynamic mechanical behavior of ultra high modulus polyethylene? are discussed in the context of our present understanding of the structure of these materials. In particular, the Takayanagi model is shown to achieve a new status in the light of direct measurements of crystal continuity from wide angle X-ray diffraction data. It is further shown that the Takayanagi model in one formulation is compatible with the Cox model for a short fiber reinforced composite. The fiber composite model offers a simple physical understanding of the fall in modulus due to the α-relaxation in terms of shear lag. This reduces the effectiveness of the continuous crystal fraction postulated in the Takayanagi model. The γ-relaxation is considered to be associated primarily with an amorphous relaxation, consistent with the conclusions of previous workers for materials of lower draw ratio.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pen.760201405
