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Trends in Radiation Polymerization (1968)

Potter, R. C. ; Schneider, Christel ; Ryska, M. ; [et al.]

Weinheim : Wiley-Blackwell

Angewandte Chemie International Edition in English 7 (1968), S. 845-856

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ISSN: 0570-0833

Keywords: Polymerization ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Previously it was generally assumed that high energy radiation could only initiate radical polymerization in solutions of monomers. However, examples of radiation-induced polymerization have recently become known that proceed via an ionic mechanism. Thus, solutions of a monomer can be polymerized ionically, preferably in the presence of a solid, at low temperatures. Suprisingly, this may also be accomplished with ultra-pure, mainly anhydrous systems, even at room temperature. The nature of the ions has not yet been fully elucidated.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/anie.196808451

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