ISSN:
0570-0833
Keywords:
Free radicals
;
Zwitterions
;
Diradicals
;
Quantum chemistry
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A knowledge of the geometries at which excited molecules return to the electronic ground state (S0) is essential for the understanding of the structures of photoproducts. Particularly good candidates are geometries corresponding to local minima on the S1 (lowest excited singlet) and T1(lowest triplet) surfaces, as well as S0-S1 conical intersections (funnels). Given sufficient effort, such geometries can nowadays be found numerically for small enough molecules. Still, it is interesting to ask whether more approximate, but also more general, statements can be made concerning the geometries at which the S0 and S1 surfaces closely approach each other. Since many of these are biradicaloid geometries, it is logical to examine the properties of biradicals and related species at some length. After reviewing the two-electron two-orbital model for molecules at biradicaloid geometries, we formulate the conditions under which the S0 and S1 surfaces touch. The results obtained for the simple model are supported by ab initio large-scale configuration interaction (CI) calculations for the twisting of ethylene in the polarizing field of a positive charge and for the twisting of charged double bonds and π-donor-to-π-acceptor single bonds, and by similar calculations for “push-pull” perturbed cyclobutadienes, some of which are predicted to have nearly degenerate S0, S1, and T1 states. The likely consequences of these results for the detailed description of the mechanisms of cis-trans isomerization, the formation of twisted internal charge-transfer (TICT) states, proton translocation, and possibly of the initial step in vision, as well as for the understanding of the regiospecificity of singlet photocycloaddition, are summarized.
Additional Material:
16 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/anie.198701701
