ISSN:
0741-0581
Keywords:
Crystal structure analysis
;
Electron diffraction
;
Organic crystals
;
Electron microscopy
;
Life and Medical Sciences
;
Cell & Developmental Biology
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Natural Sciences in General
Notes:
Electron crystallography of small organic molecules, i.e., electron diffraction crystal structure analysis, has been long recognized to possess definite advantages over neutron and x-ray diffraction techniques for the investigation of microcrystalline preparations. Quantitative application of the technique to real structural problems, on the other hand, had been hindered initially by an inadequate theoretical model. Yet, as demonstrated in this review of the methodology, the adequate recognition of limiting factors due to n-beam dynamical scattering and crystal deformation permits design of optimal diffraction experiments which yield intensity data suitable for ab initio structure analysis. Representative crystallographic analyses discussed here underscore the utility of this technique as a probe of organic molecular structure at atomic resolution.
Additional Material:
14 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jemt.1060020203