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Terpenes and terpene derivatives, XXXIV. Synthesis of rac-porosadienone (1995)

Weyerstahl, Peter ; Schwope, Ina

Weinheim : Wiley-Blackwell

Liebigs Annalen 1995 (1995), S. 191-193

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ISSN: 0947-3440

Keywords: Porosadienone ; Eudesmane, 6(7→8)-abeo- ; Terpenes ; Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: (±)-Porosadienone (9) is easily synthesized by starting from (±)-2,6-dimethylcyclohexanone via indenone 1 and dienone 4. All compounds (rac-4-6 and rac-9) with the α,β,γ,δ-dienone system are very prone to air oxidation forming the corresponding mono epoxides rac-7, rac-8, rac-10, and rac-11.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jlac.199519950126

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