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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 104 (1971), S. 461-472 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Transition Metal Chalcogen Compounds Diphenyldithiophosphinato Complexes of Vanadium(III), Vanadium(IV) and Molybdenum(VI)The preparation and properties of the compounds [(C6H5)2PS2]2MoO2 (3), [(C6H5)2PS2]2-VO (4) and [(C6H5)2PS2]3 V (5) are described. Their vibrational and electronic spectra are reported. The parameters 10 Dq = 13 200/cm and B = 395/cm were calculated from the electronic spectrum of the vanadium(III) compound.
    Notes: Die Darstellung und Eigenschaften der Verbindungen [(C6H5)2PS2]2MoO2 (3), [(C6H5)2PS2]2-VO (4) und [(C6H5)2PS2]3 V (5) werden beschrieben. Die Schwingungs- und Elektronenspektren werden mitgeteilt und letztere mit der Kristallfeldtheorie interpretiert. Für die Vanadin(III)-Verbindung lassen sich aus den Übergängen ν1(3T1g→3T2g) und ν2(3T1g(F) → 3T1g(P)) die Werte für 10 Dq 13200/cm und B 395/cm berechnen.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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