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Silicenium-Ylid-Reaktionen der Lithio-aminofluorsilane (1978)

Klingebiel, Uwe

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 111 (1978), S. 2735-2737

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ISSN: 0009-2940

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Silicenium-Ylide Reactions of Lithio-aminofluorosilanesLithio-aminofluorosilanes are formed in the reaction of monoorganoaminofluorosilanes with butyllithium if either bulky or mesomeric stabilizing substituents are present. In the reaction of lithio-aminofluorosilanes with polar compounds LiF is eliminated and addition to the intermediate sila-imine is observed.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19781110731

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