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Übergangsmetall-Fulven-Komplexe, XII. Über (Azulen)tricarbonylchrom(0)-Komplexe (1978)

Edelmann, Frank ; Behrens, Ulrich

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 111 (1978), S. 3001-3003

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ISSN: 0009-2940

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Transition Metal Fulvene Complexes, XII. (Azulene)tricarbonylchromium(0) ComplexesThe synthesis of (azulene)tricarbonylchromium(0) (2) and tricarbonyl(4,6,8-trimethylazulene)-chromium(0) (3), the first azulene derivatives of hexacarbonylchromium, is described. The Cr(CO)3 group is coordinated to the five-membered ring of the azulene. Nucleophilic addition of CH3Li to 3 leads to the tricarbonyl(1,7 - 10-η-2,4,6,6-tetramethylbicyclo[5.3.0]deca-2,4,7,9-tetraen-1-yl)-chromate anion as salt 4.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19781110829

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