ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Complex Chemistry of Reactive Organic Compounds, XXII: Organometallic Cyclopentadienylations with Diazocyclopentadienes. Syntheses of (η-Halocyclopentadienyl)iron ComplexesThe tetracarbonyliron halides (CO)4Fe(σ-C3F7)I (2) and (CO)4FeX2 [X = Br: 4; X = I: 5] react with diazocyclopentadiene (1a) and its derivatives 1b-e to yield (η-monohalocyclopentadienyl)iron complexes (η-C5R4X)Fe(CO)2L (3a-d, 6a, b, 8) [R = H, Cl, Br, C6H5; X = Br, I; L = C3F7, Br, I] and 1,1′-dibromoferrocene (7a). In addition to the analytical and spectroscopic characterization, the constitution of (η-C5H4I)Fe(CO)2I (6b) has been proved chemically.
Notes:
Die Tetracarbonyleisen-halogenide (CO)4Fe(σ-C3F7)I (2) und (CO)4FeX2 [X = Br: 4; X = 1: 5] reagieren mit Diazocyclopentadien (1a) und seinen Derivaten 1b-e unter Bildung der (η-Monohalogencyclopentadienyl)eisen-Komplexe (η-C5R4X)Fe(CO)2L (3a-d, 6a, b, 8) [R = H, Cl, Br, C6H5;X = Br, I;L = C3F7, Br, I] und von 1,1′-Dibromeferrocen (7a). Über die analytische und spektroskopische Charakterisierung der Produkte hinaus ist die Konstitution von (η-C5H4I)Fe(CO)2I (6b) auch chemisch bewiesen.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19781110913
