ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Dispirocyclobutanes and Propellanes from 1,2-BisenollactonesElectronically excited biphthalidylidene (1) and isocoumarino-isocoumarin (5) are trapped by electron-Poor stilbenes and by 1,3-dienes to give the dispirocyclobutanes 3, 8, 9, 11, 12 and the heterocyclic [4.4.2]propellanes 6 and 14 resp. The unusual tetraspirocyclobutane 4 is formed upon photodimerization of 1 as a by-product. The structures of the products have been established primarily by high-field, 1H-NMR spectroscopy and in part by chemical transformations.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19811140539