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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 114 (1981), S. 1983-1990 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dispirocyclobutanes and Propellanes from 1,2-BisenollactonesElectronically excited biphthalidylidene (1) and isocoumarino-isocoumarin (5) are trapped by electron-Poor stilbenes and by 1,3-dienes to give the dispirocyclobutanes 3, 8, 9, 11, 12 and the heterocyclic [4.4.2]propellanes 6 and 14 resp. The unusual tetraspirocyclobutane 4 is formed upon photodimerization of 1 as a by-product. The structures of the products have been established primarily by high-field, 1H-NMR spectroscopy and in part by chemical transformations.
    Type of Medium: Electronic Resource
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