ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Hydridoiridium(III) Complexes with Terminal and Bridging Thio- and Selenocyanate1)The thio- and selenocyanato complexes (Ph3P)2(CO)(Cl)(H)IrX 1 (X = SCN) and 2 (X = SeCN) and 2 (X = SeCN) have been prepared from the corresponding tetrafluoroborato- and trifluoromethanesulfonato-compounds (X = BF4, CF3SO3). The SCN ligand in 1 is S-bonded. 2 was obtained as a mixture of linkage isomers. The reaction of 2 with the tetrafluoroborato-complex (Ph3P)2(CO)(Cl)(H)IrFBF3 gives the salt [(Ph3P)2(OC)(Cl)(H)Ir—SeCN—Ir(H)(Cl)(CO)(PPh3)2]+BF-4 which contains the selenocyanate-bridged cation as a mixture of stereoisomers.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19811140633
