ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Element-Organic Amine/Imine Compounds, XXII. λ3-Phosphazene Complexes of Zerovalent PlatinumThe reaction of Pt(COD)2 (COD = 1,5-cyclooctadiene) with the λ3-phosphazene RR'N—P=NR, R = (CH3)3C, R' = (CH3)3Si(1), gives the platinum(0) complex PtL3 (2) (L = λ3-phosphazene 1) whose structure has been elucidated by an X-ray analysis. 2 is used for the synthesis of the platinum(0) compounds PtL2L' (L' = R3M, M = P→b) (3) and PtLL2' (L' = R3P) (4).
Notes:
Die Umsetzung von Pt(COD)2 (COD = 1,5-Cyclooctadien) mit dem λ3-Phosphazen RR'N—P=NR, R = (CH3)3C, R' = (CH3)3Si(1), ergibt den Platin(0)-Komplex PtL3 (2) (L = λ3-Phosphazen 1), von dem eine Röntgenstrukturanalyse angefertigt wurde. Die Synthese der Platin(0)-Verbindungen PtL2L' (L' = R3M, M = P→b) (3) und PtLL2′ (L' = R3P) (4) erfolgte aus 2.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19821150203
