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Metallcarbonyl-Synthesen, XII. Tetracarbonyl(η5-pentamethylcyclopentadienyl)vanadium (1982)

Herrmann, Wolfgang A. ; Kalcher, Willibald

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 115 (1982), S. 3886-3889

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ISSN: 0009-2940

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Metalcarbonyl Syntheses, XII. Tetracarbonyl(η5-pentamethylcyclopentadienyl)vanadiumThe hitherto unknown halfsandwich complex tetracarbonyl(η5-pentamethylcyclopentadienyl)vanadium (3) is easily accessible in 45% yield upon reaction of hexacarbonylvanadium (1) with pentamethylcyclopentadiene (2). Photolysis of 3 as well as reduction and subsequent protonation yield the dinuclear derivative 4 of composition (η5-C5Me5)2V2(CO)5.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19821151220

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