ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Dicarbonyl Rhodium(I) Complexes with Nurleobases and NucleosidesThe reaction of [Rh(CO)2CI]2 with various nucleobases and nucleosides gives the complexes (OC)2Rh(L)CI (1) (L = 9-methylguanine, hypoxanthine, cytosine, 1-methylcytosine, guanosine, 1-methylguanosine, inosine, adenosine, cytidine, 7-deazaadenosine) and (OC)2CIRh(guanine)-RhCl(CO)2 (2). The coordination of the nucleobases to the rhodium atom is discussed on the basis of the 1H NMR spectra.
Notes:
Durch Umsetzung von [Rh(CO)2Cl]2 mit verschiedenen Nucleobasen und Nucleosiden wurden die Komplexe (OC)2Rh(L)CI (1) (L = 9-Methylguanin, Hypoxanthin, Cytosin, 1-Methylcytosin, Guanosin, 1-Methylguanosin, Inosin, Adenosin, 7-Desazaadenosin, Cytidin) und (OC)2CIRh-(Guanin)RhCl(CO)2 (2) erhalten. Die Koordination der Nucleobasen an das Rhodiumatom wird an Hand der 1H-NMR-Spektren diskutiert.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19831160410
