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Zur Elektronenstruktur des 1,5-Methano-cyclodecapentaens (1986)

Roth, Wolfgang R. ; Sustmann, Reiner

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 119 (1986), S. 751-753

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ISSN: 0009-2940

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: On the Electronic Structure of 1,5-Methano-cyclodecapentaeneThe He(I) photoelectron spectrum of 1,5-methano-1,3,5,7,9-cyclodecapentaene (Bicyclo-[5.3.1]undeca-1,3,5,7,9-pentaene) (2) is recorded and compared with that of 1,6-methanocyclodecapentaene (1). The orbital sequence in 2 is derived from MO-perturbational consideration. The PE spectrum does not provide arguments for a resonance stabilization of 2.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19861190233

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