ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
On the Configurational and Substituent Dependence of the Pt—Cl Stretching Frequencies and of the 31P NMR Parameters in Substituted cis- and trans- Dichlorobis(triphenylphosphane)platinum(II) CompoundsCorrelations between substituent constants σ, Pt — Cl vibrational frequencies and 31P NMR parameters 1J[195Pt,31P] und δ[31P] for compounds of the type cis- and trans-{Pt-[P(aryl)(aryl′)(aryl″)]2 Cl2} (aryl, aryl′, aryl″ = substituted phenyl rings) are reported and discussed with respect to bonding properties.
Notes:
Zusammenhänge zwischen Substituenten-Konstanten σ, Pt—Cl-Valenzschwingungsfrequenzen und 31P-NMR-Parameter 1J[195Pt, 31P] und δ[31P] für die Verbindungen des Typs cis- und trans-{Pt[P(aryl)(aryl′)(aryl″)]2 Cl2} (aryl, aryl′, aryl″ = substituierte Phenyl-Ringe) werden beschrieben und im Hinblick auf die Bindungseigenschaften diskutiert.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19861190521