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McMurry-Reaktion der 2-Alkyl-3-ethoxyacroleine (1986)

Dormagen, Walter ; Breitmaier, Eberhard

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 119 (1986), S. 1734-1736

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ISSN: 0009-2940

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: McMurry Reaction of 2-Alkyl-3-ethoxyacroleinsMcMurry reductive coupling of 2-alkyl-3-ethoxyacroleins 1 yields 2,5-dialkylhexadienedials 6. (E) Configuration at the 2,3- and 4,5-double bonds of these dialdehydes is derived from three-bond carbon-13 proton coupling. A mechanism similiar to that discussed for McMurry coupling of carbonyl compounds is proposed.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19861190526

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