ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
(Phthalocyaninato)rhodium(II) Adducts with Nitrogen basesDilithiophthalocyanine (PcLi2) and di-μ-chloro-bis(1,5-cyclooctadiene)rhodium, [Rh(COD)Cl]2, react with the nitrogenous bases L = n-butylamine (bu), pyridine (py), 4,4′-bipyridine (bpy), and pyrazine (pyz) to form the corresponding hexacoordinated complexes PcRh(L)2, which were characterized by IR, FIR, UV/VIS, and ESR spectroscopy as well as their thermogravimetric (TG/DTA) data. Bridged complexes [PcRh(L)]n (L = pyz, bpy) could not be synthesized.
Notes:
Dilithiophthalocyanin (PcLi2) und Di-μ-chloro-bis(1,5-cyclooctadien)rhodium, [Rh(COD)Cl]2, reagieren mit den Stickstoffbasen L = n-Butylamin (bu), Pyridin (py), 4,4′-Bipyridin (bpy) und Pyrazin (pyz) zu hexakoordinierten PcRh(L)2-Komplexen. Die Charakterisierung der Komplexe erfolgt durch IR-, FIR-, UV/VIS- und ESR-Spektroskopie sowie durch Thermogravimetrie (TG/DTA). Die Darstellung überbrückter Komplexe [PcRh(L)]n (L = pyz, bpy) gelang nicht.
Additional Material:
4 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19881210207
