ISSN:
0009-2940
Keywords:
Alkanetellurenyl halides
;
Tris(trimethylsilyl)methanetellurenyl halides
;
Methyl tris(trimethylsilyl)methyl telluride
;
Phenyl tris(trimethylsilyl)methyl telluride
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Tris (trimethylsilyl)methanetellurenyl Halides (Me3Si)3 CTex (X = Cl, Br, I): Synthesis of Stable Alkanetellurenyl HalidesThe first stable and isolable alkanetellurenyl halides, tris(trimethylsilyl)methanetellurenyl chloride, bromide, and iodide (1a-c) are obtained quantitatively by halogenolysis of bis[tris-(trimethylsilyl)methyl] ditelluride with SO2Cl2, Br2, and I2, respectively. Their synthetic potential is examplified by transformation to methyl tris(trimethylsilyl)methyl telluride (2) and phenyl tris(trimethylsilyl)methyl telluride (3).
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19891220707
