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Nitroxide (Aminyloxide), XLII: Die Isolierung des ersten OC-verknüpften Dimeren eines Vinylnitroxids (1989)

Aurich, Hans Günter ; Keßler, Wilfried

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 122 (1989), S. 2395-2396

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ISSN: 0009-2940

Keywords: Nitrone, oxidation of ; Vinylhydroxylamine, oxidation of ; Vinyl nitroxide, dimerization of ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Nitroxides (Aminyl Oxides), XLII. - The Isolation of the First OC-Bonded Dimer of a Vinyl NitroxideVinyl nitroxide 2, formed by oxidation of nitrone 1, with lead dioxide, affords the OC dimer 3. Oxidation of 1 proceeds rather slowly. A high oxidation potential is found for 1. However, if vinyl nitroxide 2 is generated from the vinylhydroxylamine 4, the aldehyde 7 is formed by a complex reaction sequence.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19891221228

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