ISSN:
0009-2940
Keywords:
Key Words: Phosphaalkines / Diels-Alder reaction / λ3-Phosphinines
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Phosphorus Compounds with Unusual Coordination, 43. - Highly Functionalized λ3-Phosphinines from 5,5-Dimethoxycyclopentadienes and Kinetically Stabilized Phosphaalkyne1,2,3,4-Tetrachloro-5,5-dimethoxycyclopentadiene (5) is transformed into the λ3-phosphinine 10 by reaction with the phosphaalkyne 6; the bicyclic compound 7 is assumed to be the intermediate of the process. In an analogous way the reaction 14 + 6 yields the isomeric λ3-phosphinines 15 and 17.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19901230445