Electronic Resource
Weinheim
:
Wiley-Blackwell
Berichte der deutschen chemischen Gesellschaft
124 (1991), S. 87-88
ISSN:
0009-2940
Keywords:
Alkylidenesulfur difluoride oxide
;
Carbon-sulfur double bond
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Hg[C(COF) = SF2 = O]2 is prepared by the reaction of FCO — CH = SF2 = O with HgF2. This compound represents the third known example of an alkylidenesulfur difluoride oxide. Its molecular structure is the same as that of the most abundant of the three isomers of FCO-CH = SF2 = O. This is assumed to be the result of weak intramolecular Hg… O contacts. With the exception of the fluorine atoms bound to sulfur, all atoms lie approximately in one plane.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240114
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