ISSN:
0009-2940
Keywords:
Azines
;
Bis(azines)
;
Macrocycles
;
Tetraazapolyenes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The new macrocyclic bis(azine) 2 forming yellow microcrystals has been prepared in 72% yield by treating the diketone 1 with hydrazine hydrate under high-dilution conditions. In contrast to the UV/Vis spectrum of the “open-chain” azine 4, that of 2 shows characteristic features of a polyene chromophore containing (Z)-configurated double bonds.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240335