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  • 1
    Electronic Resource
    Electronic Resource
    Decacarbonyl(μ3;-η2-‖-1,4-dimethoxy-2-butyne)triiron, an Iron Cluster with Unusual Structure (1991)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 773-775 
    Details
    ISSN: 0009-2940
    Keywords: Alkyne complexes ; Clusters ; Iron complexes ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reaction of undecacarbonyl(acetonitrile)triiron (1) with 1,4-dimethoxy-2-butyne (2) yields the alkyne complexes decacarbonyl(μ3;-η2-Verbar-1,4-dimethoxy-2-butyne)triiron (3) and nonacarbonyl(μ3;-η2;-⊥-1,4-dimethoxy-3-butyne)triiron (4). The crystal structure determination of 2 shows that the alkyne ligand is coordinated strictly parallel to one iron-iron edge.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19911240417
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