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Substituent Effects on Folding in Cyclotetraphosphane (1991)

Schoeller, Wolfgang W. ; Busch, Thilo

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 1369-1371

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ISSN: 0009-2940

Keywords: Cyclotetraphosphanes, substituent effects, vibrational analysis ; Calculations, ab initio ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Ab initio quantum chemical calculations evidence a very flat potential hypersurface for folding of parent cyclotetraphosphane. This is in accord with a corresponding vibrational analysis. Electronegative substituents increase folding of the fourmembered ring system.

Additional Material: 4 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19911240610

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