ISSN:
0009-2940
Keywords:
Organogallium compounds
;
Organoindium compounds
;
Intramolecular base stabilization
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The intramolecularly stabilized five-coordinated organogallium and organoindium compounds {2,6-[(CH3)2NCH2]2C6H3H3}-GaMe2 (1), {2,6-[(CH3)2NCH2]2C6H3}InR2 (2-4), and {2,6-[(C2H5)2-NCH2]2C6H3}InEt2 (5) have been synthesized from {2,6-bis-[(dimethylamino)methyl]phenyl)}lithium or from {2,6-bis[(diethylamino)methyl]phenyl}lithium and the corresponding diorganogallium or diorganoindium chloride. The 1H-, 13C-NMR and mass spectra of the new compounds are reported and discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240714