ISSN:
0009-2940
Keywords:
Bond activation, C — H, C — C
;
Transition-metal ions
;
Tandem mass spectrometry
;
Geminal dialkyl effect
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Depending on the internal energy content, due to the operation of a geminal dialkyl effect, the Fe+ -mediated dehydrogenation of α,α-dimethyl-substituted ketones preferably involves the more substituted alkyl chain.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240733