ISSN:
0009-2940
Keywords:
Charge-transfer complexes
;
Conductivity
;
Redox systems
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Multi-Step Redox Systems, LVI. - Crystal Structures and Conductivities of the CT Complexes TTF/2-X-5-Me-DCNQI (X = Cl, Br, I) from Tetrathiafulvalene and 2-Halogeno-N,N′-dicyano-5-methyl-1,4-benzoquinone DiimineIn contrast to microcrystalline powders single crystals of the title complexes show low conductivities (&10; 〈 sigma-5 Scm-1). These properties are based on a peculiar mixed stack arrangement of donor and acceptor molecules within the crystal lattice (space group P21/n).
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240921