ISSN:
0009-2940
Keywords:
Sulfur-carbon compounds, bicyclic
;
Titanocene chelate complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Sulfur Compounds, 143. - Synthesis and Characterisation of the New Bicyclic Sulfur-Carbon Compounds C6H8S8, C4H4S7, and C4H4S8The reaction of Cp4Ti2C2S4 (1) with two equivalents of the bissulfenyl chloride 1,2-C2H4(SCl)2 affords the new bicyclic compound C6H8S8 (2). Treatment of 1 with one equivalent of SxCl2 (x = 1, 2) results in Cp2TiC2S5 (3) and Cp2TiC2S6 (4), respectively, which on reaction with 1,2-C2H4(SCl)2 give the asymmetric bicyclic polysulfides C4H4S7 (5) and C4H4S8 (6), respectively.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240941