ISSN:
0009-2940
Keywords:
Flash vacuum thermolysis
;
Retro-ene reaction
;
Silanamine
;
Silanimine
;
Vacuum gas solid reaction
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The unhindered silanimines 1,1-dimethyl-N-phenylsilanimine (2) and N-isopropyl-1,1-dimethylsilanimine (10) have been generated by flash vacuum thermolysis of the N-allylsilanamine 1 and vacuum gas-solid reaction of the 1-chlorosilanamine 9, respectively. The silanimines 2 and 10 have been characterized by MS as well as by chemical trapping to yield 3 or dimerization to the cyclodisilazane 11.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921250615