ISSN:
0009-2940
Keywords:
μ-Cyano(2,3-naphthalocyaninato)iron(III)
;
Potassium dicyano(2,3-naphthalocyaninato)ferrate(III)
;
Dichloro(2,3-naphthalocyaninato)iron(III)
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Potassium dicyano(2,3-naphthalocyaninato)ferrate(III), K[2,3-NcFe(CN)2] (2), reacts in water with elimination of KCN to form μ-cyano(2,3-naphthalocyaninato)iron(III), [2,3-NcFe(CN)]n (4a). Dichloro(2,3-naphthalocyaninato)iron(III), 2,3-NcFeCl2 (3), reacts with KCN to yield also [2,3-NcFe(CN)]n (4b). Both compounds 4a and 4b show similar IR spectra with a typical blue-shifted CN valence frequency caused by a bridging function of CN-. Compounds 4a and 4b also show almost identical 57Fe-Mössbauer spectra which, however, might be interpreted with a Fe(+II) oxidation state of the iron. The measured magnetic moment of 4 however clearly proves the expected oxidation state +III of the iron in [2,3-NcFe(CN)]n (4). Compounds 4a and 4b both exhibit good semiconducting properties (σRT ∼ 10-3 S/cm) without additional external oxidative doping. The property is quite similar to that of the known μ-cyano(phthalocyaninato)iron [PcFe(CN)]n (σRT ∼ 10-2 S/cm).
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19931261135
