ISSN:
0009-2940
Keywords:
Charge-transfer experiments
;
Tandem mass spectrometry
;
Diazene
;
Potential energy surface
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Collision experiments demonstrate that isodiazene (H2NN) and its radical cation are viable molecules in the gas phase. The mass-spectrometric experiments are complemented by extensive ab-initio MO calculations using the GAUSSIAN-2 procedure in order to map out relevant parts of the potential energy surface of H2N2 (singlet) and H2N2+· (doublet).
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19931261227