ISSN:
0009-2940
Keywords:
Silyl triflates
;
Polysiloxanes
;
Polycarbosilanes
;
Polysilylenealkynes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Bis(trifluoromethylsulfonyloxy)organosilicon Compounds as Synthetic Materials for New Silicon PolymersThe new polycarbosilanes, polysiloxanes, and polysilylenealkynes 1c-6c were obtained by condensation of electrophilic α,ω-bis(trifluoromethylsulfonyloxy)organosilicon compounds 1b-6b with nucleophiles such as organolithium and organomagnesium compounds. The required silyl triflate derivatives 1b-6b have been prepared by reaction of the corresponding amino-, allyl-, or phenylsilanes 1a-6a with trifluoromethanesulfonic acid.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941270604
