ISSN:
0009-2940
Keywords:
Rhenium(V), nitrido(tetra-tert-butylphthalocyaninato)-
;
Rhenium(V), nitrido(phthalocyaninato)-
;
Phthalocyaninato complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
4-tert-Butylphthalodinitrile (1) reacts with ammonium perrhenate, NH4ReO4, to yield nitrido(tetra-tert-butylphthalocyaninato)rhenium(V), (tBu)4PcReN (2), which is characterized by IR, UV/Vis, CV, MS, 1H and 13C NMR, and elemental analysis. It shows good solubility in common organic solvents. In solution 2 is assumed to be monomeric whereas in the solid state also dimers or higher aggregates are present. From the NMR spectra it is concluded that different constitutional isomers of 2 are formed but not in the expected ratio of a statistical distribution. By analogy with 2, the already known nitrido(phthalocyaninato)rhenium(V), PcReN (3), is prepared for comparison.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941270919
