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Selective Activation of Aromatic C - H Bonds with Lithium Atoms at 77 K (1995)

Tacke, Matthias

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 128 (1995), S. 91-92

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ISSN: 0009-2940

Keywords: C - H bond activation ; Lithum atoms ; Cocondensation ; Aryllithium ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: In the presence of donor bases like THF lithium atoms are able to activate benzene derivatives under cryogenic reaction conditions. Only ring-metalated products and solid lithium hydride are formed selectively. The thermodynamically favored product benzyllithium or biphenyl generated by dimerization of free phenyl radicals are not found. This is one of the very few examples of metal atoms undergoing a C - H activation without further photoexcitation.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19951280114

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