ISSN:
0009-2940
Keywords:
Rhodium complex, dinuclear
;
Phosphaalkyne
;
Trimerization
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The new dinuclear rhodium complex 4 was synthesized by reaction of [(iPr3P)2RhCl]2 (1) or [(iPr3P)2(CH2=CH2)RhCl] (2) with 2-tert-butyl-1-phosphaacetylene (3) in 58% yield. An X-ray analysis reveals that in 4 a 1,3,6-triphosphahexadiene-1,6-diyl chain is bound to each of the two rhodium atoms in an η1,η3 manner.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19951280714