ISSN:
0009-2940
Keywords:
Orthoamides
;
Trisaminomethanes, tricyclic
;
Guanidinium cation, alkylation
;
Copper(II) complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The orthoamides 2a, b (R = Ph and PhCH2) have been prepared by alkylation of the guanidinium salt 4+BPh4- with PhNa and PhCH2Na, respectively. The crystal structures of the two orthoamides have been determined by X-ray crystallography. Their reaction with CuCl2 gives 1:1 complexes. The crystal structure of the complex with 2a shows a square planar geometry around the copper atom with η2-2a and two chlorides and weak interactions two the third nitrogen atom and a C-H bond of 2a in the axial positions.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19961290106
