ISSN:
0009-2940
Keywords:
Suzuki coupling
;
π Complexes, organometallic
;
π Complexes, dihaloarene
;
Ruthenium complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The synthesis of a terphenyl derivative complexed by the cationic moiety Cp*Ru+ by Suzuki coupling of [Cp*Ru(BrC6H4Br)]OTf with phenyl boronic acid under catalysis of Pd(PPh3)4 in a DME-water mixture at 85°C in quantitative yield is reported. The stable coupling product 3 was characterized by X-ray crystal structure analysis.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19961291103