ISSN:
0009-2940
Schlagwort(e):
Catalysis
;
Oxidations
;
Transition metals
;
Sodium percarbonate
;
1, 2-Dichloroethane
;
Chemistry
;
Inorganic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The screening of metal chlorides and metal acetylacetonates as catalysts for the oxidation of 1-indanol by sodium percarbonate (at reflux in 1,2-dichloroethane in the presence of small amounts of Adogen 464) has been carried out. The efficiency of the process depended on the nature of the transition metal and its oxidation state but, except for iron, was not greatly influenced by the nature of the ligands. Good conversions and yields have been obtained using PdCl2, RhCl3, RuCl3 and, particularly, MoO2(acac)2 as catalysts.
Zusätzliches Material:
2 Tab.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/cber.19971301116