ISSN:
0075-4617
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Intramolecular Rearrangements of Bicyclo[2,2, heptanes, XI1). Rearrangement of 1- Methyl-7,2-norbornanecarbolactone in Sulfuric AcidIn the presence of concentrated sulfuric acid 1-methyl-7,2-norbornanecarbolactone (1) rearranges to 3exo-methyl- and 1-methyl-2,6-norbornanecarbolactones (2 and 5). The structure of the hitherto unknown lactone 5 is established.
Notes:
1-Methyl-norbornan-carbolacton-(7.2) (1) lagert sich unter dem Einfluß konzentrierter Schwefelsäure in 3 exo-Methyl- und 1-Methyl-norbornan-carbolacton-(2.6) (2 und 5) um. Die Struktur des bislang unbekannten Lactons 5 wird bewiesen.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.19697220121