ISSN:
0075-4617
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Synthese of Phosphinimine CompoundsA number of new phosphinimine compounds of s-triazines is obtained by the reaction of triamino-s-triazine (9) with triphenylphosphine and halogenes (table 1) or of trichloromelamine (17, table 2) or hexachloromelamine (26, table 3) with tertiary phosphines. The components react in the absence of dehydrohalogenating compounds. Only one reaction step is necessary for the formation of the products. All these methods give pure products in good yields.
Notes:
Eine Reihe neuer Phosphinimin-Derivate von s-Triazinen (Tab. 1) wird in einer Stufe mit groβer Reinheit und hohen Ausbeuten aus Triamino-s-triazinen (9), Triphenylphosphin und Halogenen in Abwesenheit von Halogenwasserstoff bindenden Verbindungen sowie aus Trichlormelamin (17, Tab. 2) oder Hexachlormelamin (26, Tab. 3) und tertiären Phosphinen erhalten.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.19697290114