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Synthesis of (-)-Cytoxazone, a Novel Cytokine Modulator Isolated from Streptomyces sp. (1999)

Seki, Masanori ; Mori, Kenji

Weinheim : Wiley-Blackwell

Liebigs Annalen 1999 (1999), S. 2965-2967

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Details

ISSN: 1434-193X

Keywords: Amino alcohol ; Asymmetric synthesis ; Cell signaling ; Dihydroxylations ; Heterocycles ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Cytoxazone [(4R,5R)-(-)-5-hydroxymethyl-4-(4-methoxyphenyl)-2-oxazolidinone, 1], a new immunosuppressant, was synthesized by starting from p-methoxycinnamyl alcohol (2) employing the Sharpless asymmetric dihydroxylation as the key reaction in 26% overall yield (7 steps).

Type of Medium: Electronic Resource

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