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A New Approach to N-Methylaspartic, N-Methylglutamic, and N-Methyl-α-aminoadipic Acid Derivatives (2000)

Burger, Klaus ; Spengler, Jan

Weinheim : Wiley-Blackwell

Liebigs Annalen 2000 (2000), S. 199-204

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ISSN: 1434-193X

Keywords: Hexafluoroacetone ; N-Methylaspartic acid ; N-Methylglutamic acid ; N-Methyl-α-aminoadipic acid ; N-Methylthiazol-4-yl-α-amino acids ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: N-Methylaspartic acid derivatives and its homologues are obtained by a stereoconservative one-pot procedure from hexafluoroacetone-protected aspartic and glutamic acid, 2a and 2b, respectively. α-Aminoadipic acid (5c) and its derivative 6c are accessible from the corresponding glutamic acid derivative 9b by a Wolff rearrangement. A variety of homochiral N-methylamino acids, 5 and 12, and their derivatives, 6 and 8-11, become readily available by the new synthetic concept.

Type of Medium: Electronic Resource

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