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Synthese von (R)-Lasiodiplodin aus Polyhydroxybuttersäure (1990)

Braun, Manfred ; Mahler, Ulrike ; Houben, Sabine

Weinheim : Wiley-Blackwell

Liebigs Annalen 1990 (1990), S. 513-517

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ISSN: 0170-2041

Keywords: Macrolide ; Polyhydroxybutyric acid ; (R)-Lasiodiplodin ; Botrysdiplodia theobromae Pat. ; Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Synthesis of (R)-Lasiodiplodin from Polyhydroxybutyric AcidThe twelve-membered macrolide (R)-lasiodiplodin (1), a fungal metabolite of Botrysdiplodia theobromae, has been synthesized in a nine-step procedure. (R)-1,3-Butanediol (6), which is easily available by reductive depolymerization of the biopolymer polyhydroxybutyric acid (PHB), proves itself as a suitable enantiomerically pure building block.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jlac.199019900198

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