ISSN:
0941-1216
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
α-Methylated Fencholenic and α-Campholenic Aldehyde - Synthesis and ReactionsThe syntheses of α-methylated fencholenic (6a) and α-campholenic aldehyde (6b) via the corresponding azomethines (5) are reported. Aldol condensations of 6a, b with following reductions give the allylic alcohols (12-16) and hydrogenation the saturated alcohols (17-21) with strong woody odors, some of the allylic alcohols resembling that of sandal wood. Simple reduction or oxidation of 6a, b give the alcohols (24, 27), ethers (26), esters (23, 25, 28) and ketones (29) which have interesting woody odors with spicy, earthy and herbaceous notes.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19933350807
