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[1,5] Sigmatropic shifts in a 1,4-diphospholylbenzene (1990)

Mercier, François ; Mathey, François

New York, NY [u.a.] : Wiley-Blackwell

Heteroatom Chemistry 1 (1990), S. 187-190

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ISSN: 1042-7163

Keywords: Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The central phenylene ring of 1,4-bis(3,4-dimethylphosphol-1-yl)benzene undergoes [1,5] shifts around both phospholyl rings above 150°C to give 1,4-bis(3,4-dimethyl-5H-phosphol-2-yl)benzene, which can be trapped by tolane, [CpFe(CO)2]2, or Mn2 (CO)10 to yield the corresponding bis-1-phosphanor-bornadiene, bis-phosphaferrocene, or bis-phosphacymantrene respectively.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hc.520010211

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